How to Make an Oil Resistant Surface

August 23 2019 Non-stick, Anti-fouling

Oil slick on water

New coatings are making surfaces more oil resistant.  How does that benefit me?  

Low surface tension liquids like oil or organic solvents are designed to wet the surface for maximum lubrication or solvation.  But what if you're separating organics or don't want the surface to wet?  That can be a problem for stainless steel or even common analytical flow path surfaces like PTFE.  That's because most coatings or traditional water repelling materials like PTFE aren't effective in repelling oil.  Here's what oil and hexadecane look like when placed on a PTFE surface.

Hexadecane on teflon 29.7 degree contact angle-401247-edited.png oil on teflon 48.5 degree contact angle-515333-edited.png

Fluoro Based Materials: An Oil Resistant Surface

New fluoro based coatings offer both excellent hydrophobicity and oleophobicity, making oil and solvent separations more effective.  This improves test sensitivity and can improve process efficiency.  

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Oil droplet contact angle measurement is an effective way to evaluate the oil and solvent resistance of a surface.  The higher the contact angle, the more oil and solvent resistant the surface will be.  We bonded our new fluoro material, Notak™, to a rough stainless steel surface to see if the contact angle would increase.  The fluoro material made a big difference in contact angle, making the stainless steel an oleophobic surface.

hexadecane on rough fluoro 92.6 degree-142340-edited-531970-edited oil on rough fluoro 95.5 degree-075556-edited-682056-edited

High Temperature Capability

Given the nature of analytical systems refining or cleaning for that matter, we can expect the surface to be exposed to elevated temperatures.  PTFE is high temperature limited and can fail in many high temperature applications.  We exposed the fluoro Notak surface to elevated temperature (300°C) for several hours to gauge the impact to wettability and contact angle on various surfaces.  The graph below shows consistent contact angle readings over the 90+ hour test.  PTFE would have failed at 250°C. 

Oxidative stability, oleophobicity fluoro surface.png

The Benefits of an Oil Resistant Surface

Surface interaction can impact corrosion, fouling, analytical sampling results, filtration and medical device performance.  So it's important to understand how to manage the fluid interaction with critical flow path surfaces.  Oil or solvent resistant surfaces can benefit a wide range of processes:

  • More effective oil/water separations in hydrocarbon processing and produced water applications
  • Prevent fouling in refinery processes
  • Less maintenance and fouling of stack monitoring probes
  • Improved analytical separations
  • Improved filtration
  • Easier mold release in plastic manufacturing

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